Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    总第115期    2008年10月

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文章编号:1004-0609(2008)10-1858-06
超重力条件下电沉积金属镍的结构与性能
刘 婷1, 2,郭占成1, 3,王 志1,王明涌1

(1. 中国科学院过程工程研究所 多相复杂系统国家重点实验室,北京 100190;
2. 中国科学院 研究生院,北京 100049;
3. 北京科技大学 循环与生态冶金教育部重点实验室,北京 100083
)

摘 要:

在超重力垂直于电极表面的情况下,研究超重力场对水溶液金属电沉积镍箔的组织结构和性能的影响,利用原子力显微镜(AFM)和X射线衍射仪(XRD)对沉积镍箔的表面形貌和晶体结构进行观察。结果表明:超重力场下的镍箔晶粒细化,表面更平整,当重力系数为354时,表面粗糙度由常重力下的20.9 nm降低到4.9 nm;并且随着重力系数的增加,沉积镍箔的晶体结构从有择优取向结构转变为无特定的择优取向结构。力学性能测试表明,当重力系数为354时,沉积镍箔的硬度和抗拉强度分别达到HV 898和944 MPa,比常重力下分别提高了HV 604和646 MPa。

 

关键字: 镍箔;超重力场;重力系数;电沉积;结构;性能

Structure and properties of electrochemically deposited nickel under high gravity field
LIU Ting1, 2, GUO Zhan-cheng1, 3, WANG Zhi1, WANG Ming-yong1

1. State Key Laboratory of Mutiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
3. Laboratory of Ecological and Recycle Metallurgy, University of Science and Technology Beijing, Beijing 100083, China

Abstract:In a high gravity field vertical to electrode surface, the effects of high gravity on the microstructure and properties of Ni film deposited electrochemically were investigated. With atomic force microscopy (AFM) and X-Ray diffraction. The results reveal that the surface structure of nickel film deposited under high gravity condition was more uniform and smoother compared with that in normal gravity condition; under G = 354, the roughness decreased sharply from 20.9 nm to 4.9 nm, and crystal grains diminished with the increasing of gravity coefficient. Furthermore, its crystal structure transforms from tropism to non-tropism with gravity coefficient. The hardness and tensile stress of nickel film are raised markedly to HV898 and 944 MPa when the gravity coefficient was up to 354 g, higher than those in normal gravity condition by HV604 and 646 MPa, respectively.

 

Key words: nickel film; high gravity field; gravity coefficient; electro-deposition; structure; property

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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