Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第2期    总第107期    2008年2月

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文章编号:1004-0609(2008)02-0372-05
铜基材硝酸银溶液浸镀银的沉积过程
魏喆良1, 2,邵艳群2,王 欣2,唐 电2

(1. 福州大学 机械工程及自动化学院,福州 350108;2. 福州大学 材料研究所, 福州 350002)

摘 要:

利用电化学方法和场发射扫描电子显微分析方法,对硝酸银溶液中铜基材浸镀银的沉积速率及其沉积物的形貌变化进行研究。结果表明,整个沉积过程可分为外延生长、过渡生长和枝晶生长3个阶段。在不同的沉积阶段,银晶层的沉积速率和形貌也不同。在沉积初期吸附银原子呈现外延生长;在基材表面未被银初晶层覆盖之前,则主要以二维方式沿基材表面铺展;之后,便在初晶层的局部位置以枝晶方式突出生长,最终得到疏松且呈海绵状的银镀层。

 

关键字: 浸镀银;电沉积;置换反应

Deposition process of immersion silver plating onto
WEI Zhe-liang1, 2, SHAO Yan-qun2, WANG Xin2, TANG Dian2

1. College of Mechanical Engineering and Automation, Fuzhou University, Fuzhou 350108, China;2. Institute for Materials Research, Fuzhou University, Fuzhou 350002, China

Abstract: The deposition rate and morphology of immersion silver plating onto copper substrate in silver nitrate aqueous solution were studied by galvanic current method and field emission scanning electron microscopy (FE-SEM). The results show that the whole deposition process can be divided into three stages:extending growth,transitional growth and dendritic growth. The deposition rate and morphology of Ag deposit are all different in each stage. Initially,the adhesive Ag atoms grow along the lattice of copper substrate. Secondly,the substrate is spread with initial silver crystal accompanied with two-dimension growth. Finally,coarse and sponge-like silver plating is prepared with dendritic growth.

 

Key words: immersion silver; electrodeposition; displacement

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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