Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第3期    总第108期    2008年3月

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文章编号:1004-0609(2008)03-0388-06
Zn对铸态Mg-Mn合金力学性能和腐蚀性能的影响
尹冬松1,张二林2,曾松岩 1

((1. 哈尔滨工业大学 材料科学与工程学院,哈尔滨 150001;2. 中国科学院金属研究所,沈阳 110016)

摘 要:

研究Zn对Mg-Mn合金微观组织、力学性能和在Hank’s溶液中腐蚀性能的影响。结果表明:Zn可以明显细化Mg-Mn合金的铸态组织,当合金中Zn含量(质量分数)为3%时,合金的晶粒尺寸由700~900 μm减小到50~80 μm。合金的力学性能也随Zn含量的增加而显著提高;Zn含量为3%时,拉伸强度提高128.8 MPa,屈服强度提高42.6 MPa,伸长率提高1倍多。在Mg-Mn合金中加入 1%~2%的Zn,能够增强Mg-Mn合金钝化膜的稳定性,使Mg-Mn合金腐蚀速度显著降低。但是,当Zn含量增至3%时,钝化膜变得不稳定,腐蚀速度增加,耐蚀性能降低。

 

关键字: 镁合金;锌;微观组织;力学性能;腐蚀

Effect of Zn on mechanical properties and corrosion properties of
YIN Dong-song 1, ZHANG Er-lin 2, ZENG Song-yan 1

1. School of Materials Science and Technology, Harbin Institute of Technology, Harbin 150001, China;2. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Abstract:The effect of Zn on the microstructure, mechanical properties and corrosion properties in Hank’s solute on of as-cast Mg-Mn alloy was studied. The results indicate that the addition of Zn element can significantly refine the grain size of cast Mg-Mn alloy. When Zn content is increased up to 3% (mass fraction), the grain size of the cast alloy decreases from 700−900 μm to 50−80 µm. Meanwhile, the mechanical properties of the alloy also increase with increasing Zn content. When Zn content is 3%, the ultimate tensile strength and the yield strength are increased by 128.8 and 42.6 MPa, respectively, while the elongation is increased twice. Addition of Zn element to Mg-Mn alloy can stabilize the passivation film, which mainly contributes to the low corrosion rate of Mn-Mn-Zn alloy. However, when the Zn content is over 3%, the passivation film becomes unstable, which results in a relatively high corrosion rate.

 

Key words: magnesium alloy; zinc; microstructure; mechanical property; corrosion

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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