Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第3期    总第108期    2008年3月

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文章编号:1004-0609(2008)03-0383-05
原位生长碳纳米管对炭/炭复合材料导热性能的影响
周建伟,廖寄乔,王占锋

(中南大学 粉末冶金国家重点实验室,长沙 410083)

摘 要:

以炭纤维表面原位生长有碳纳米管(Carbon nanotubes, CNTs)的针刺毡体作为前驱体制备出生长有CNTs的炭/炭复合材料,并与在同样工艺条件下通过致密化最终热处理得到的纯炭/炭复合材料进行对比。结果表明,在密度几乎相同的情况下,生长有CNTs的炭/炭复合材料的室温Z轴热导率约为11.10 W/(m·K),几乎为纯炭/炭复合材料的室温Z轴热导率(6.28 W/(m·K))的2倍,其原因可能在于:CNTs可以有效改善炭纤维和热解炭之间的界面特性,明显减少炭/炭复合材料中纤维和热解炭界面处周裂纹的出现,还可以诱导热解炭形成一种拥有更高导热率更易石墨化的粗糙结构。

 

关键字: 碳纳米管;炭/炭复合材料;热导率;热解炭

Effect of in situ grown carbon nanotube on thermal conductivity of carbon/carbon composites
ZHOU Jian-wei, LIAO Ji-qiao, WANG Zhan-feng

State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Abstract:Carbon nanotubes(CNTs)-grown carbon/carbon (C/C) composites which have CNTs in situ grown on carbon fibers of needled carbon fiber felts, and pure carbon/carbon composites were fabricated by the chemical vapor infiltration (CVI) method to investigate the effect of CNTs on room temperature Z direction thermal conductivity of C/C composites. Thermal conductivity of samples were tested by laser flash method. The results show that the room temperature Z direction thermal conductivity of CNTs-grown C/C composites is about 11.10 W/(m•K) which is generally 2 times that of pure C/C composites with nearly the same density. The reason is that the favorable effect of CNTs on room temperature Z direction thermal conductivity of C/C composites is achieved by better interfacial properties and formation of high-textured pyrocarbon that has better graphitizability and higher thermal conductivity than other types of pyrocarbon.

 

Key words: C/C composites; thermal conductivity; pyrocarbon

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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