Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第12期    总第105期    2007年12月

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文章编号:1004-0609(2007)12-2046-08
电解铝液中Al2O3夹杂物的形成机理
贺永东1, 2,张新明1,陈明安1

(1. 中南大学 材料科学与工程学院,长沙 410083;2. 金川集团有限公司,金昌 737100)

摘 要:  介绍铝电解机制对电解铝液中形成Al2O3夹杂物的影响,分析铝液中Al2O3夹杂物形成的机理,推算CO2对铝液扩散的质量传递方程,描述效应处理过程对铝液中Al2O3夹杂物形成过程的影响。利用PersonWaddington电流效率模型测算电解铝液中可能形成的Al2O3夹杂物最大值。结果表明:电解过程生成的Al2O3夹杂物对铝液的污染,是短流程工艺影响铝熔体冶金质量的主要根源。

 

关键字: 电解铝液;Al2O3夹杂物;CO2;阳极效应;冶金遗传

Formation mechanism of Al2O3 inclusion in electrolytic liquid-Al
HE Yong-dong1, 2, ZHANG Xin-ming1, CHEN Ming-an1

1. School of Materials Science and Engineering, Central South University,Changsha 410083, China;2. Jinchuan Company Limited Group, Jinchang 737100, China

Abstract:The effect of mechanism of Al electrolyte on the formation of Al2O3 inclusion in electrolytic liquid-Al was introduced. The mechanism of formation of dioxide inclusions in liquid-Al was analyzed. A mass transporting equation of CO2 diffusion into liquid-Al was proposed. The formation of Al2O3 inclusion during manipulating anode effect was described. With Person—Waddington model, the probable maximum dioxide inclusions in electrolytic liquid-Al was quantitative measured. It is suggested that the alumina contained in the electrolytic liquid-Al is the main source of debasing metallurgical quantity.

 

Key words: electrolytic liquid-Al; Al2O3 inclusion; CO2; anode effect; metallurgical heredity

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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