Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第7期    总第100期    2007年7月

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文章编号: 1004-0609(2007)07-1143-06
真空钎焊金刚石界面碳化物的形貌
卢金斌1, 2,徐九华2

(1. 中原工学院 材料与化学工程学院,郑州 450007;
2. 南京航空航天大学 机电学院,南京 210016
)

摘 要:

采用Ni-Cr、Ag-Cu-Ti和Ti-Zr-Ni-Cu等钎料分别对单晶金刚石与基体进行真空钎焊。SEM、EDS和XRD等分析结果表明,在一定的钎焊温度、时间及真空度下,金刚石与所有钎料均形成化学冶金结合,在不同钎料界面形成的碳化物的种类、数量和形貌分布却显著不同; Ni-Cr合金钎料在界面处形成片状的Cr3C2和针状Cr7C3;Ag-Cu-Ti钎料则生成不连续分布块状TiC,Ti-Zr-Ni-Cu生成的是呈鹅卵石状连续分布的TiC。

 

关键字: 金刚石;碳化物;真空钎焊;钎料

Morphology of carbide on diamond interface by vacuum brazing
LU Jin-bin1, 2, XU Jiu-hua2

1. School of Materials and Chemical Engineering, Zhongyuan University of Technology,
Zhengzhou 450007, China;
2. College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics,
Nanjing 210016,China

Abstract:Using Ni-Cr, Ag-Cu-Ti, and Ti-Zr-Ni-Cu alloy as fillers diamond was brazed on matrix in vacuum furnace. By SEM, EDX and XRD analysis, it is shown that at certain brazing temperature, duration and vacuum level, chemical bonding takes place on the interface between the diamond and all the fillers. The kind, amount, morphology and distribution of carbides formed are different on different filler interface. Some slice-like Cr3C2 and acicular Cr7C3 carbides exist on the interface of Ni-Cr, discontinuous-lump-like TiC carbide exists on the interface of Ag-Cu-Ti, and continuous-cobble-like TiC exists on the interface of Ti-Zr-Ni-Cu.

 

Key words: diamond; carbide; vacuum brazing; filler

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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