Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

您目前所在的位置:首页 - 期刊简介 - 详细页面

中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第1期    总第94期    2007年1月

[PDF全文下载]        

    

文章编号:1004-0609(2007)01-0035-04
稀磁半导体Zn1−xNixO的室温铁磁性
彭 坤1, 2,周灵平1,胡爱平1,唐元洪1

(1. 湖南大学 材料科学与工程学院,长沙 410082;
2. 中南大学 粉末冶金国家重点实验室,长沙 410083
)

摘 要:

利用溶胶-凝胶方法制备不同成分的Zn1−xNixO(x=0.05,0.10,0.15)稀磁半导体材料,产物由直径约70 nm的六边形颗粒组成。利用振动样品磁强计测量了样品的磁学性能,发现在室温条件下存在明显的铁磁性,且随着镍浓度的增加,样品的饱和磁化强度增加,但样品的单个镍原子的磁矩是逐渐下降的。X射线衍射分析结果表明,样品中不存在镍及镍的氧化物,且晶格常数随镍含量的增加而略有增大,并利用M—T曲线测量Zn0.9Ni0.1O居里温度为575 K左右,表明其磁性来源于稀磁半导体。

 

关键字: 稀磁半导体;ZnO;铁磁性

Room temperature ferromagnetism in
Zn1-xNixO diluted magnetic semiconductor
PENG Kun1, 2, ZHOU Ling-ping1, HU Ai-ping1, TANG Yuan-hong1

1. College of Materials Science and Engineering, Hunan University,Changsha 410082, China;
2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Abstract:A series of Zn1-xNixO(x=0.05, 0.10, 0.15) diluted magnetic semiconductors are fabricated by using sol-gel method, and the products consist of hexagonal nanoparticles with about 70 nm in diameter. The measurement of magnetism was carried out by a vibrating samples magnetometer (VSM), it was found that the samples show ferromagnetism under the room temperature, and with the increase of Ni-ion content, the saturated magnetization increase, but the averaged atomic magnetic moments decrease. The X-ray diffraction results show that there is not any pure nickel or nickel-oxide in the samples and the lattice increases with the content of Ni-ion. It was determined that the Curie temperature of Zn0.9Ni0.1O at about 575 K by M—T curves, which confirmed Zn1−xNixO is ferromagnetism under room-temperature.

 

Key words: diluted magnetic semiconductor; ZnO; ferromagnetism

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中国科学技术协会 主办:中国有色金属学会 承办:中南大学
湘ICP备09001153号 版权所有:《中国有色金属学报》编辑部
------------------------------------------------------------------------------------------
地 址:湖南省长沙市岳麓山中南大学内 邮编:410083
电 话:0731-88876765,88877197,88830410   传真:0731-88877197   电子邮箱:f_ysxb@163.com