Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 22    Special 1    October 2012

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Microstructure and electrical properties of sol−gel derived Ni-doped CaCu3Ti4O12 ceramics
ZHANG Cheng-hua1, 2, 3, 4, 5, ZHANG Ke1, 5, XU Hong-xing1, SONG Qi1, 5, YANG Yong-tao1, 6,
YU Ren-hong1, 6, XU Dong1, 2,

1. School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, China;
2. Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors,
Chinese Academy of Sciences, Beijing 100083, China;
3. State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University,
Xi’an 710049, China;
4. State key Laboratory of Electronic Thin Films and Integrated Devices,
University of Electronic Science and Technology of China, Chengdu 610054, China;
5. Changzhou Engineering Research Institute of Jiangsu University, Changzhou 213000, China;
6. Changzhou Ming Errui Ceramics Co., Ltd., Changzhou 213102, China

Abstract:Dielectric properties and varistor performance of sol−gel prepared Ni-doped calcium copper titanate ceramics (CaCu3NixTi4O12+x, x=0, 0.1, 0.2, 0.3) were investigated. SEM and XRD were used in the microstructural studies of the specimens and the electrical properties were investigated for varistors. XRD patterns show that the CCTO ceramics were single phase with no Cu-rich phase. SEM results indicated that the samples had smaller grain sizes than those synthesized by traditional solid-state reaction methods. The experimental results show that the highest dielectric constant and lower dielectric loss occur when x=0.2. When x=0.3, the lowest leakage current is obtained and the maximum value reaches 0.295; meanwhile, the lowest threshold voltage and nonlinear coefficient are found, the minimum values of them are 1326 V/mm and 3.1, respectively.

 

Key words: CaCu3Ti4O12; sol−gel; capacitors; memory devices; electrical properties; microstructure; phase transition

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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