Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 21    No. 7    July 2011

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Rapid synthesis of Ti(C, N) powders by mechanical alloying and
subsequent arc discharging
YUAN Quan1, 2, ZHENG Yong1, YU Hai-zhou1, 2

1. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics,
Nanjing 210016, China;
2. College of Mechanical and Materials Engineering, China Three Gorges University, Yichang 443002, China

Abstract:Ti(C,N) powders were synthesized by mechanical alloying (MA) from a mixture of pure titanium and graphite under a nitrogen atmosphere in a planetary mill. Effects of arc discharging on phase transformation and microstructure of MA powders milled for 1−7 h were explored. The results show that Ti(C,N) powders were prepared after mechanical milling for 1 h and subsequent arc discharge treatment, whereas the synthesis reaction did not occur in 7 h by mechanical milling alone. The ions produced during arc discharging interacted with powder particles and accelerated the diffusion of atoms and the nucleation on the surface of the as-milled powder, which results in fast synthesis of Ti(C,N) powders. The formation mechanisms of the two synthesis processes are self-propagating reactive synthesis.

 

Key words: Ti(C,N) powders; mechanical alloying; self-propagating reactive synthesis

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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