Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 21    No. 7    July 2011

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Preparation and oxidation property of ZrB2-MoSi2/SiC coating on carbon/carbon composites
ZHANG Wu-zhuang, ZENG Yi, GBOLOGAH Lemuel, XIONG Xiang, HUANG Bai-yun

State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Abstract:To improve the oxidation resistance of carbon/carbon composites, ZrB2-MoSi2/SiC coating on the carbon/carbon substrate was prepared. The inner coating of SiC was prepared by pack cementation and the outer coating of ZrB2-MoSi2 was prepared by slurry painting. The phase compositions and microstructures of the coating were characterized by XRD and SEM, respectively. The preparation and the high temperature oxidation property of the coated composites were investigated. The results show that the outer coating of carbon/carbon composites is composed of ZrB2, MoSi2 and SiC phases. The mass losses of the ZrB2-MoSi2/SiC coated samples with SiC nano-whiskers after 30 h and 10 h of oxidation at 1 273 K and 1 773 K were, respectively, 5.3% and 3.0%. The ZrB2-MoSi2/SiC coated samples exhibit self-sealing performance and good oxidation resistance at high temperature.

 

Key words: carbon/carbon composites; ZrB2-MoSi2; SiC; coating; oxidation

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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