Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 21    No. 5    May 2011

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Removal of boron from metallurgical grade silicon by
electromagnetic induction slag melting
LUO Da-wei1, LIU Ning1, LU Yi-ping1, ZHANG Guo-liang1, LI Ting-ju1, 2

1. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China;
2. Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education,
Dalian University of Technology, Dalian 116024, China

Abstract:A new purification process was developed to remove impurities in metallurgical grade silicon (MG-Si) by electromagnetic induction slag melting (EISM). Vacuum melting furnace was used to purify boron in different slag systems. The results show that the removal effect in SiO2-CaO-Al2O3 systems is better than that in other slag systems by EISM. The boron content in MG-Si is successfully reduced from 1.5×10−5 to 0.2×10−5 during EISM at 1 823 K for 2 h. Meanwhile, Al, Ca and Mg elements in MG-Si are also well removed and their removal efficiencies reach 85.0%, 50.2% and 66.7%, respectively, which indicates that EISM is very effective to remove boron and metal impurities in silicon.

 

Key words: metallurgical grade silicon; slag system; partition ratio

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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