Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 20    No. 10    October 2010

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Synthesis and physico-chemical properties of new green electrolyte 1-butyl-3-methylimidazolium perchlorate
WANG Xiao-dan(王晓丹)1, 2, WU Wen-yuan(吴文远)1, TU Gan-feng(涂赣峰)1, JIANG Kai-xi(蒋开喜)1, 3

1. School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China;
2. College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, China;
3. Beijing General Research Institute of Mining and Metallurgy, Beijing 100044, China

Abstract:1-butyl-3-methylimidazolium perchlorate ([BMIM]ClO4) was synthesized by two steps with N-methylimidazolium. Some physico-chemical properties, such as density, surface tension, viscosity, electrical conductivity as well as electrochemical window, were investigated and solvent performance was also studied. The results show that this kind of ionic liquid is an excellent electrolyte with low viscosity, high electrical conductivity and wide electrochemical window. In addition, [BMIM]ClO4 is soluble in most conventional solvents and some metal oxides have high solubility in it, which lays the foundation of direct electrolysis of metal oxides in this ionic liquid.

 

Key words: room temperature ionic liquid; 1-butyl-3-methylimidazolium perchlorate; electrolyte; solubility

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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