Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 20    No. 8    August 2010

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Structural characteristics and dielectric properties of
glass-ceramic nanocomposites of (Pb,Sr)Nb2O6-NaNbO3-SiO2
WANG Lei(王 磊), ZHANG Qing-meng(张庆猛), DU Jun(杜 军)

Advanced Electronic Materials Institute, General Research Institute for Nonferrous Metals, Beijing 100088, China

Abstract:The structure and dielectric properties of (Pb,Sr)Nb2O6-NaNbO3-SiO2 glass-ceramics with different Pb and Sr contents were investigated. The XRD pattern of glass-ceramics without Sr substitution is different from that with Sr substitution, which indicates the existence of orthorhombic phase in the latter ones. TEM bright field observation shows nanosized microstructures, while for samples with Sr, typical eutectic microstructure with separated crystallized bands is found in the glass matrix. Dielectric properties measurement of the samples indicates an obvious improvement of dielectric constant, dielectric loss, DC field and temperature dependence of dielectric constant when the molar ratio of Sr to Pb is 4׃6.

 

Key words: dielectric properties; nanocomposite; (Pb, Sr)Nb2O6; NaNbO3; glass-ceramics

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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