Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 3    No. 4    December 1993

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ACTIVATION MECHANISM OF AlCl3 DURING THE LEACHING OF Cu-Ni ORE WITH Fe Cl3
Wu; Wenjian Chen; Zhong Jiang; Hanying Yang; Songqin

Department of Chemistry; Central South Unirersity of Technology; Changsha 410083; China

Abstract:After Cu-Ni ore powder pre-soaked in AlCl3 solution.the leaching ratios of copper and nickel can increase obviously.By X-ray diffraction analyses,electron energy spectrum analyses and electrochemical experiments,it is affirmed that,the activation of aluminum ion includes two aspects:one is the surface change of the ore by the absorption of hydrolysates,and the oth- er is the change of semiconductor characteristics of the metal sulfides by impurity aluminum ion entering the lattice,so that leaching reactions are accelerated.

 

Key words: oxidative leaching; copper-nickel sulfide ore; aluminium chloride; activation

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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