中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
Vol. 3 No. 4 December 1993 |
(1.Department of Surface Science and Corrosion Engineering; University of Science and Technology Beijing; Beijing 100083; China;
2.Northeastern Unirersity; Shenyang 110006; China)
Abstract:The effects of 5 wt.-% Al and 10 wt.-% Al on the sulfidation behaviour of the Fe-25Cr alloy in H2S-H2 gas mixtures in the temperature range of 700~900 C has been studied.The sulfidation resistance of Fe-25Cr was improved and the sulfide scale morphologies,composition and structure of Fe-25Cr changed remarkably.The sulfidation kinetics of the alloys with alu- minium obeyed basically the parabolic law after an initial period of reaction time.The sulfida- tion mechanism of the Fe-Cr-Al alloy has been proposed.
Key words: Al; Fe-25Cr; H2S-H2 gas mixtures; sulfidation