Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 4    No. 1    March 1994

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CHLORINATION OF Ni-Cr ALLOYS IN Cl2 ENVIRONMENT AT 575℃
Tu Jiangping; Mao Zhiyuan; Li Zhizhang

Department of Materials Science and Engineering; Zhejiang University; Hangzou 310027 ; china

Abstract:The chlorination of nickel-chromium alloys in chlorine environment at 575℃ was investi-gated using thcrmogravimetric analysis and cxamination of the corrcaion prixlucts using SEM,EDS, XRD, XPS and chemical analysis. In a dry chlorine environment at high temperature,the corrooion resulted from the formation of volatile clilorides. The rcaction kinetics followed acomplex pattern which can be approximated by initial parabolic rate law to linear rate law afterlong time exposure.

 

Key words: chlorination chloride reaction preduct scale vapor pressure

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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