Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 9    No. 3    September 1999

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Phase and structure of polycrystal Sr0.69La0.31F2.31+SrS solid electrolyte material
Tian Yanwen(田彦文), Ma Ping(马 平), Zhang Xin(张 新), Zhai Yuchun(翟玉春)

School of Materials and Metallurgy,Northeastern University, Shenyang110006, P. R. China

Abstract:The phase and the structure of polycrystal material, which was prepared by calcining the co-precipitated fluoride powder of Sr and La with a ratio of 0.69∶0.31 mixed with SrS powder, were investigated by X-ray diffraction and electron probe scanning. In the materials, three phases were found, they are Sr0.69La0.31F2.31 solid solution phase with a pure SrF2 cubic structure whose lattice constant is 5.843 A , SrS single phase with a NaCl cubic structure, and an unknown phase that is produced by the interaction of SrS and co-precipitated powder. It was also found that SrS has no influence on the structure of Sr0.69La0.31F2.31 solid solution.

 

Key words: X-ray diffraction; electron probe; polycrystal Sr0.69La0.31F2.31+SrS material; phase structure

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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