Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 17    Special 1    November 2007

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Kinetics of non-isothermal precipitation process of perovskite phase in oxidized Ti-bearing blast furnace slag
WANG Ming-yu(王明玉)1, HE Yue-hui(贺跃辉)2, WANG Xue-wen(王学文)1,
LOU Tai-ping(娄太平)3, SUI Zhi-tong(隋智通)3

1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;
2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;
3. School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China

Abstract:Kinetics of non-isothermal precipitation process and crystal growth of perovskite phase in oxidized Ti-bearing slag were investigated. The oxidized slag was obtained by blowing the air into the molten Ti-bearing blast furnace slag through a lance. The experimental results show that the cooling rate has important effect on precipitation and growth of perovskite phase in oxidized slag; the lower cooling rate is in favor of not only the increase of the volume fraction of perovskite phase, but also the growth of perovskite phase grain sizes. The particle coarsening in non-isothermal process has important effect on the crystal growth of perovskite phase. The relative volume fraction of perovskite phase could be approximately described by JMAK equation, and the experiential expression of the average crystal radius of perovskite phase was also obtained.

 

Key words: Ti-bearing slag; oxidation; crystallization; kinetics

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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