Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 20    Special 1    May 2010

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Effective removal of heavy metals from aqueous solutions by orange peel xanthate
LIANG Sha(梁 莎)1, GUO Xue-yi(郭学益)1, FENG Ning-chuan(冯宁川)2, TIAN Qing-hua(田庆华)1

1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;
2. School of Basic Medical Science, Ningxia Medical College, Yinchuan 750004, China

Abstract:Preparation of orange peel xanthate and its adsorption behaviors of five heavy metals (Cu2+, Cd2+, Pb2+, Zn2+ and Ni2+) were studied. FTIR spectra, Zeta potentials and TG analysis were used to characterize prepared orange peel xanthate. Effects of various parameters including equilibrium pH, initial metal ion concentration and adsorption time on the adsorption processes for the five metal ions were investigated. It was found that for all five metal ions, the adsorption isotherms agreed Langmuir model very well and the maximum adsorption capacities of Cu2+, Cd2+, Pb2+, Zn2+ and Ni2+ were obtained as 77.60, 76.57, 218.34, 49.85 and 15.45 mg/g, respectively. All adsorption processes can attain equilibrium within 20 min and kinetics was well fitted by psesudo-second order equation. It is proposed that the adsorption mechanism was complexation.

 

Key words: orange peel xanthate; adsorption; heavy metals

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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