Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 10    No. 4    August 2000

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Leaching kinetics of rare earth from black weathering mud
with hydrochloric acid①
CHI Ru-an(池汝安)1, ZHU Guo-cai(朱国才)1, TIAN Jun(田 君)2

1. Institute of Nuclear Energy Technology, Tsinghua University, Beijing 102201, P.R.China;
2. Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang 330029, P.R.China

Abstract:The affecting factors of leaching rate such as reacting temperature, mud particle size and concentration of reagents were determined by studying the leaching kinetics of rare earth from black weathering mud. The apparent activation energy is 9.08 kJ/mol from calculating the experimental data. The results show that the leaching process can be described by the shrinking core model and the leaching rate is controlled by diffusion of reacting reagents and reaction product in the porous solid layer. The leaching kinetics is established as:K=7.50×10-5×exp(-9 080/RT)/r20.

 

Key words: kinetics; black weathering mud; leaching rare earth

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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