Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 10    No. 3    June 2000

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Oxide formation on sputtered Ni-3Cr-10Al nanocrystalline coating①
CHEN Guo-feng(陈国锋), LOU Han-yi(楼翰一)

State Key Laboratoryfor Corrosion and Protection of Metals, Institute of Corrosion and
Protection of Metals, Chinese Academy of Sciences, Shenyang110015, P.R.China

Abstract:The oxide formation on the sputtered Ni-3Cr-10Al nanocrystalline coating at 900℃and 1 000℃in air has been studied. The results indicated that an oxide scale composed of NiAl2O4and Al2O3was formed on the sputtered Ni-3Cr-10Al nanocrystalline coating whereas a unitary Al2O3scale was not formed even when the Al content was high in the sputtered coating. The formation of NiAl2O4was directly related to the precipitation of Ni3Al in the coating during oxidation process. It was suggested that the precipitation of Ni3Al contributed to the formation of NiO and therefore NiO could react with Al2O3and form NiAl2O4. With increasing oxidation temperature, the effect of Ni3Al precipitation on the formation of NiAl2O4decreased.

 

Key words: Ni-3Cr-10Al; sputtering; nanocrystalline coating; oxidation

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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