Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 20    No. 4    April 2010

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Non-isothermal microwave leaching kinetics and absorption characteristics of primary titanium-rich materials
XIA Hong-ying(夏洪应)1, 2, PENG Jin-hui(彭金辉)1, 2, NIU Hao(牛 浩)1, 3, HUANG Meng-yang(黄孟阳)3,
ZHANG Zheng-yong(张正勇)1, 2, ZHANG Ze-

1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology,
Kunming 650093, China;
2. Key Laboratory of Unconventional Metallurgy, Ministry of Education,
Kunming University of Science and Technology, Kunming 650093, China;
3. Yunnan Copper Co., Ltd., Kunming 650102, China;
4. School of Information Science and Engineering, Yunnan University, Kunming 650091, China

Abstract:The non-isothermal leaching kinetics of primary titanium-rich material by microwave heating was investigated, and the temperature-pressure curves of leaching system and microwave absorption characteristics of mixture solutions before and after leaching were measured. The research of non-isothermal kinetics was evaluated by the leaching rate of Fe and the total apparent velocity equation of the non-isothermal kinetics of leaching for primary titanium-rich material by microwave heating was obtained. It is shown from the temperature-pressure curves that the high temperature and high pressure of closed leaching system are favorable to the enhancement of the leaching rate of Fe. Microwave absorption characteristics of mixture solutions before and after leaching show that there are abrupt changes of microwave absorption characteristics for 15% HCl solution and the mixture solution after leaching by 20% HCl.

 

Key words: primary titanium-rich material; non-isothermal kinetics; microwave absorption characteristic

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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