Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 20    No. 3    March 2010

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Adjustment on gibbsite and boehmite co-precipitation from
supersaturated sodium aluminate solutions
WANG Zhi(王 志)1, YANG Liu(杨 柳)1, 2, ZHANG Juan(张 娟)1, 2,
GUO Zhan-cheng(郭占成)1, ZHANG Yi(张 懿)1

1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology,
Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Abstract:Gibbsite is the usual precipitation product from alumina refineries with either Bayer or sintering process. However, the advantage of boehmite precipitation over gibbsite precipitation is the significant energy saving in the subsequent calcination step. The current investigation takes a pragmatic approach to measure precipitation ratios, determine product phase, morphology and particle size distribution, and assess the impacts and adjustment capability of main parameters such as seed, temperature, ethanol medium, and supersaturation on the precipitation kinetics and alumina hydrate type during co-precipitation process. The results clarify that gibbsite and boehmite both can be precipitated from supersaturated sodium aluminate solutions simultaneously, and the competitive formation between Al(OH)3 and γ-AlOOH determines the main precipitate phases from pregnant liquor. Boehmite seeds, high temperature and ethanol addition can promote the boehmite precipitation and improve the mass fraction of boehmite in products. Co-precipitation changes the multimodal distribution of seeds to a normal and well distribution of products, and the particle size is more than several times that of seeds.

 

Key words: sodium aluminate solutions; co-precipitation; boehmite; gibbsite

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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