Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 20    No. 1    January 2010

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Composition and morphology of complicated copper oxalate powder
FAN You-qi(樊友奇), ZHANG Chuan-fu(张传福), WU Jian-hui(邬建辉), ZHAN Jing(湛 菁), YANG Ping(杨 平)

School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China

Abstract:In Cu(Ⅱ)-C2O42--NH3-NH4+-H2O system, complicated copper oxalate powders were synthesized by coordination- precipitation process with ammonium oxalate as precipitating agent. The composition and morphology of the powders were characterized by chemical analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), infrared spectroscopy (IR), and thermogravimetric and differential thermal analysis (TGA-DTA). The effects of temperature, copper ion concentration and pH value were investigated. The experimental results show that pure copper oxalate hydrate is prepared below a critical pH value of 6.0, whereas the powder turns to be a complicated copper salt combined with NH3 over the pH value. Probable chemical formula, CuC2O4x(NH3) ∙yH2O can be assumed, where x and y relate to experimental conditions. Technological parameters, such as temperature, initial copper concentration and solution pH value, have significant effects on particle size, morphology and dispersion of the powders. Powders with various morphologies, pie shape, spindle shape and rod shape, can be synthesized under certain technological conditions.

 

Key words: copper oxalate; preparation; coordination; morphology; composition

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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