Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 19    Special 3    December 2009

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Water-soluble CdSe/ZnS quantum dots passivated by
poly(glycino amino acid) phosphazenes
ZHANG Teng(张 腾), YUAN Hui-ping(袁慧萍), SUO Hong-li(索红莉)

Key Laboratory of Advanced Functional Materials, College of Material Science and Engineering,
Beijing University of Technology, Beijing 100124, China

Abstract:Poly(organophosphazenes) have potential applications in making water-soluble and biocompatible quantum dots (QDs) due to their wide variety of properties. The CdSe QDs of green emission and the core-shell CdSe/ZnS QDs of red emission were prepared. Subsequently the trioctylphosphine oxide-stabilized CdSe/ZnS QDs were transferred from chloroform into water through a ligand exchange process with poly(glycino amino acid)phosphazenes, which can be obtained from the saponification of poly (glycino amino ester)phosphazenes at room temperature. The resulting QDs-polymer nanocomposite particles can form colloidally stable suspensions in water and exhibit good photostability.

 

Key words: polyphosphazenes; CdSe/ZnS quantum dots; water-solublity; nanocomposite particles

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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