Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 19    No. 6    December 2009

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Synthesis and electrochemical performances of LiNi0.6Co0.2Mn0.2O2 cathode materials
ZHONG Sheng-kui(钟胜奎)1, 2, LI Wei(李 伟)1, LI Yan-hong(李艳红)3,
ZUO Zheng-guang(邹正光)1, 2, TANG Xin(唐 鑫)1, 2

1. Department of Material and Chemistry, Guilin University of Technology, Guilin 541004, China;
2. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials,
Ministry of Education, Guilin University of Technology, Guilin 541004, China

Abstract:LiNi0.6Co0.2Mn0.2O2 was prepared from LiOH·H2O and MCO3 (M=Ni, Co, Mn) by co-precipitation and subsequent heating. XRD, SEM and electrochemical measurements were used to examine the structure, morphology and electrochemical characteristics, respectively. LiNi0.6Co0.2Mn0.2O2 samples show excellent electrochemical performances. The optimum sintering temperature and sintering time are 850 ℃ and 20 h, respectively. The LiNi0.6Co0.2Mn0.2O2 shows the discharge capacity of 148 mA∙h/g in the range of 3.0−4.3 V at the first cycle, and the discharge capacity remains 136 mA∙h/g after 30 cycles. The carbonate co-precipitation method is suitable for the preparation of LiNi0.6Co0.2Mn0.2O2 cathode materials with good electrochemical performance for lithium ion batteries.

 

Key words: lithium ion batteries; LiNi0.6Co0.2Mn0.2O2; cyclic voltammogram (CV)

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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