中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
Vol. 13 No. 4 August 2003 |
(1. School of Chemistry and Chemical Engineering,
Central South University, Changsha 410083, China;
2. School of Materials Science and Engineering,
Hunan University, Changsha 410082, China)
Abstract:The solutions of poly(acrylic acid)(PAA), poly(acrylic acid sodium)(PAANa) were coated on aluminium fins by roll coating method. The coatings with different crystallinity were obtained by varying baking time and temperature. Their surface crystallinity and surface tension were measured, and their spreading speed constant and equilibrium contact angle were tested also. The correlation of surface crystallinity, surface tension, spreading speed constant and surface hydrophilicity was discussed. It is demonstrated that surface tension and spreading speed constant increase, while equilibrium contact angle declines with increasing surface crystallinity of coatings, that is to say, the hydrophilicity of coatings is improved with surface crystallinity of coatings increasing.
Key words: PAA; PAANa; surface crystallinity; surface tension; hydrophilicity; spreading speed constant