中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
Vol. 13 Special 1 May 2003 |
(National Key Laboratory of Advanced Welding Production Technology,
Harbin Institute of Technology, Harbin 150001, China)
Abstract:A layer of Cu was sintered on the surface of Al2O3 ceramic before bonding, and then diffusion bonding technology was applied to bond Al2O3/Cu to Al alloy. SEM and EDS were applied to analyze the interfacial microstructures of Al2O3/Cu/Al joint. The preliminary research shows that Al/Cu interfacial microstructures are the main factor affecting joint strength. With increasing bonding temperature and time, ((Al)+θ) mixture separates out from Al alloy, and (Cu)+ γ1)mixture separates out from Cu layer. The two kinds of mixtures develop first along interface, then (Cu)+γ1) microstructure turns progressively into (ξ2 +δ) with bonding temperature and time prolonged. At the same time, ((Al)+θ) and /(ξ2 +δ) phases move gradually into base materials. The two kinds of changes result in reducing bonding strength greatly. The optimum diffusion bonding parameters are determined as follows: T=773K, t=1226s and p=6MPa, at which the tensile strength of the joint is 108MPa, and the shear strength of the joint is 45MPa.
Key words: Al alloy; Al2O3 ceramic; diffusion bonding