中国有色金属学报(英文版)
Transactions of Nonferrous Metals Society of China
Vol. 19 No. 3 June 2009 |
(College of Chemical Engineering and Materials Science, Zhejiang University of Technology,
Hangzhou 310014, China)
Abstract:Corrosion studies of a commercially pure titanium in phosphoric acid solutions at 250 ℃ were carried out by immersion test in an autoclave. At lower phosphoric acid concentration (0.1 mol/L), the corrosion was mild. At higher phosphoric concentration (1.0 mol/L) corrosion, a 25 µm-thick white corrosion products layer was formed on the samples after 24 h immersion. XRD analysis shows that the white layer consists mainly of titanium oxide phosphate hydrate (π-Ti2O(PO4)2∙2H2O). The corrosion product shows the morphology of fiber bundles. A thermodynamic analysis of the formation of the corrosion product is presented.
Key words: titanium; corrosion; phosphoric acid; high temperature and high pressure; corrosion mechanism