Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 14    No. 4    August 2004

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Kinetics of crystal growth on seeded precipitation of
sodium aluminate solutions with new device
CHEN Jin-qing(陈金清)1, ZHANG Ping-min(张平民)1, GAN Guo-yao(甘国耀)2,
YIN Zhou-lan(尹周澜)1, CHEN Qi-yuan(陈启元)1

1. School of Chemistry and Chemical Engineering,
Central South University, Changsha 410083, China;
2. Guangxi Corporation of China Aluminum Corporation, Pingguo 531400, China

Abstract:A new device was designed, which can effectively avoid the undesired nucleation and agglomeration of fineparticles on the experimental results during the seaded precipitation of sodium aluminate solution, and moreover, the experimental conditions are nearly kept constant during the experiment. With the new device, it is proven that a good result can be obtained on the kinetics study of the crystal growth in seeded precipitation of sodium aluminate solution.Experiments were carried out with the concentration of Na2O (Nk)170 g/L, the mole ratio of Na2O to Al2O3(αk) all between 1.52 to 2.01, at 65, 70, 75℃, respectively. And the kinetics equation of crystal growth of gibbsite was deduced.

 

Key words: sodium aluminate solution; seeded precipitation; crystal growth; kinetics

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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