Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 14    No. 3    June 2004

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Dechromisation of Cu-Cr alloy in acid solutions containing Cl-
XU Tao(许 涛)1, CHEN Ling(陈 玲)2, CHEN Yan(谌 岩)2,
YU Sheng-xue(于升学)2, LIU Bin(刘 彬)3, LIU Jian-hua(刘建华)3

1. Department Applied Technology, Daqing Petroleum Institute, Daqing 163318, China;
2. Department of Environmental & Chemical Engineering,
Yanshan University, Qinhuangdao 066004, China;
3. Key Laboratory of Metastable Materials Science and Technology,
Yanshan University, Qinhuangdao 066004, China

Abstract:The phenomenon, characteristics and influence factors of dechromisation of a Cu-Cr alloy in acid solutions containing Cl-were studied by means of metallographic observation, SEM/EDX, TEM and XRD. The mechanism of dechromisation of Cu-Cr alloy was discussed. The results show that dechromisation of the Cu-Cr alloy occurs at a certain temperature in solutions with H+and Cl-simultaneously. The corrosion starts initially at the interfaces between Cu phase
and Cr phase, then develops gradually into the centers of Cr phase. It is also revealed that dechromisation rates of the Cu-Cr alloy increase with increasing concentration of H+or Cl-, and temperature of the solutions.

 

Key words: Cu-Cr alloy; dechromisation; H+; Cl-

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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