Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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Transactions of Nonferrous Metals Society of China

Vol. 18    No. 2    April 2008

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Preparation of copper arsenite and its application in purification of copper electrolyte
XIAO Fa-xin(肖发新)1, ZHENG Ya-jie(郑雅杰)1, WANG Yong(王 勇)1, 2, JIAN Hong-sheng(简洪生)1, 2, LI Chun-hua(李春华)1, 2, XU Wei(许 卫)1, 2, MA Yu-tian(马玉天)1

1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;2. Daye Nonferrous Metal Limited Co. Ltd., Huangshi 435005, China

Abstract:The preparation of copper arsenite with arsenic trioxide was presented and its application in the purification of copper electrolyte was proposed. The variables of n(OH−)/n(As), n(Cu)/n(As), NaOH concentration, reaction temperature and pH value have some effects on the yield of copper arsenite. The optimum conditions of preparing copper arsenite are that the molar ratio of alkali to arsenic is 2:1, NaOH concentration is 1 mol/L, the molar ratio of copper to arsenic is 2:1, pH value is 6.0 and reaction temperature is 20 ℃. The yield of copper arsenite is as high as 98.65% under optimum conditions and the molar ratio of Cu to As in the product is about 5:4. The results of the purification experiments show that the removal rate of antimony and bismuth is 53.85% and 53.33% respectively after 20 g/L copper arsenite is added. The purification of copper electrolyte with copper arsenite has the advantages of simple technique, good purification performance and low cost.


Key words: arsenic trioxide; copper arsenite; purification; copper electrolyte

ISSN 1004-0609
CN 43-1238/TG

ISSN 1003-6326
CN 43-1239/TG

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