Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第3期    总第96期    2007年3月

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文章编号:1004-0609(2007)03-0368-05
射频反应磁控溅射制备氮化铜薄膜
肖剑荣1, 2,徐 慧1,刘小良1,李燕峰1,张鹏华2,简献忠3

(1. 中南大学 物理科学与技术学院,长沙 410083;
2. 中南大学 材料科学与工程学院,长沙 410083;
3. 上海理工大学 电气工程学院,上海 200093
)

摘 要:

使用射频反应磁控溅射法,在不同的射频功率和气体流量比下制备了氮化铜薄膜,并用X射线衍射仪和原子力显微镜对薄膜的结构进行表征。研究结果表明:薄膜呈现择优生长规律,由低气体流量比的Cu3N(111)晶面转向高分压的(100)面;薄膜的光学带隙在1.44~1.69 eV之间,电阻率在60~5.6×105 Ω∙m之间,二者都随气体流量比的增大而增大。

 

关键字: 氮化铜薄膜;晶体结构;光学带隙;电阻率

Copper nitride thin films prepared by
radio frequency magnetron sputtering
XIAO Jian-rong1, 2, XU Hui1, LIU Xiao-liang1,
LI Yan-feng1, ZHANG Peng-hua2, JIAN Xian-zhong3

1. School of Physics Science and Technology, Central South University,Changsha 410083, China;
2. School of Material Science and Engineering, Central South University,Changsha 410083, China;
3. School of Electric and Engineering,University of Shanghai Science and Technology, ShangHai 200093, China

Abstract:Copper nitride (Cu3N) thin films were deposited by reactive radio frequency magnetron sputtering under different discharge powers and gas flow ratios. The structures of films were characterized by atomic force microscopy (AFM) and X-ray diffraction spectra (XRD). The properties of films were analyzed by UV-VIS spectra and four-probe method. The results show that the films’ growth prefers (111) direction at low nitrogen press and (100) direction at high nitrogen pressure. The optical band gap of the films ranges from 1.44 to 1.69 eV, the resistivity ranges from 60 to 5.6×105Ω∙m, and they both increase with the increase of nitrogen pressure.

 

Key words: copper nitride thin films; crystal structure; optical band gap; resistivity

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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