Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中国有色金属学报(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 25    No. 2    February 2015

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Preparation and photocatalytic performance of Cu-doped TiO2 nanoparticles
Xi-jia YANG, Shu WANG, Hai-ming SUN, Xiao-bing WANG, Jian-she LIAN

Key Laboratory of Automobile Materials of Ministry of Education, College of Materials Science and Engineering,
Jilin University, Changchun 130025, China

Abstract:Cu-doped TiO2 nanoparticles with different doping contents from 0 to 2.0% (mole fraction) were synthesized through sol-gel method. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscope (FE-SEM) were used to characterize the crystalline structure, chemical valence states and morphology of TiO2 nanoparticles. UV-Vis absorption spectrum was used to measure the optical absorption property of the samples. The photocatalytic performance of the samples was characterized by degrading 20 mg/L methyl orange under UV-Vis irradiation. The results show that the Cu-doped TiO2 nanoparticles exhibit a significant increase in photocatalytic performance over the pure TiO2 nanoparticles, and the TiO2 nanoparticles doped with 1.0% Cu show the best photocatalytic performance. The improvement in photocatalytic performance is attributed to the enhanced light adsorption in UV-Vis range and the decrease of the recombination rate of photoinduced electron-hole pair of the Cu-doped TiO2 nanoparticles.

 

Key words: TiO2; Cu; nanoparticles; photocatalysis; doping; sol-gel method

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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